The Selecao have lost just one of their last 20 games across all competitions, including four successive wins without conceding a goal since their World Cup exit at the hands of Belgium.
Here, Sports Mole looks at how Tite's side could line up at the Emirates.
Talisman Neymar is set to win his 95th cap and could score his 60th international goal, but who will join him in the front three remains to be seen.
Tite took the rarely-used step of starting both Gabriel Jesus and Roberto Firmino against Argentina last month, although that experiment did not exactly work as planned so the Liverpool forward may have to settle for a place on the bench.
Walace is expected to be chosen ahead of the unmarked Allan as the holding midfielder, while Arthur is also likely to be selected in that trio. Renato Augusto, Rafinha and Paulinho are competing for the other central midfield role.
Liverpool's Fabinho is regarded as a right-back by Tite and could start there given Danilo's lack of football for Manchester City this season, while Alex Sandro and Filipe Luis are battling it out for a start on the other flank.