Getafe vs. Atletico (Tuesday, 6.30pm)
Having failed to collect a point so far, the hosts sit in 19th spot in the La Liga table, while Los Colchoneros sit on 11 points from their opening five outings.
We say: Getafe 0-2 Atletico Madrid
Given Getafe's poor start to the new season, Tuesday presents a good opportunity for Simeone's men to build confidence and return to winning ways.
While they have not been overly convincing so far, Los Colchoneros boast the quality to cruise past their hosts and put a much-needed victory on the board.
Athletic Bilbao vs. Rayo Vallecano (Tuesday, 9.00pm)
The newly-promoted outfit currently occupy 10th spot in the La Liga table with seven points from their opening five games, while Tuesday's hosts sit two points better off in fifth place.
We say: Athletic Bilbao 2-1 Rayo Vallecano
While both sides come in with confidence, the hosts boast the stronger squad and should have enough to get over the line.
Marceliino's men boast quality all over the pitch, and will look to continue their unbeaten start with a win on home turf.
Levante vs. Celta Vigo (Tuesday, 9.00pm)
With just one point from their first five games, the visitors sit in 18th spot in the La Liga table, while their hosts are only three points better off, and are also yet to win.
We say: Levante 1-1 Celta Vigo
While Levante have made a better start to the season, the losses to their squad arguably gives an established Celta Vigo XI the advantage, and this could go either way.
We opt for a low-scoring draw, as the sides could cancel each other out in their bids to climb the table.