If Carlo Ancelotti's side take all three points from the game and second place Marseille fail to beat Bastia, then they will be crowned champions for the first time since 1994.
PSG will have to secure the win without several key players including Salvatore Sirigu, Marco Verratti and David Beckham, of all whom were sent off in the 1-0 win over Evian TG last week. Thiago Motta will also miss out due to suspension.
Ancelotti's side are in excellent form going into the game and have lost just one of their last seven matches in Ligue 1.
The visitors are in a similar good run taking five points from a possible nine in their last three games, which has eased their relegation worries.
Possible starting lineups
PSG: Douchez, Jallet, Thiago Silva, Alex, Maxwell, Pastore, Chantome, Matudi, Lavezzi, Menez, Ibrahimovic
Valenciennes: Penneteau, Lala, Rose, Angoua, Bong, Sanchez, Gomis, Sankhare, Melikson, Danic, Nguette
Sports Mole says: 3-1