Arsenal have been handed a home game against Southampton after the third-round draw of the League Cup was made on Wednesday evening.
Liverpool will play Middlesbrough at Anfield, while holders Manchester City will host Sheffield Wednesday.
Chelsea will meet Bolton Wanderers at Stamford Bridge, Everton travel to Swansea City and Tottenham Hotspur entertain Nottingham Forest.
Elsewhere, Manchester United's conquerors, MK Dons, will play at home to Bradford City, who beat Leeds United on Wednesday evening.
All games will be played during the week commencing September 22.
DRAW IN FULL:
Chelsea vs. Bolton Wanderers
Arsenal vs. Southampton
West Bromwich Albion vs. Hull City
Crystal Palace vs. Newcastle United
Leyton Orient vs. Sheffield United
Cardiff City vs. AFC Bournemouth
Sunderland vs. Stoke City
Derby County vs. Reading
Liverpool vs. Middlesbrough
Milton Keynes Dons vs. Bradford City
Manchester City vs. Sheffield Wednesday
Burton Albion vs. Brighton and Hove Albion
Swansea City vs. Everton
Shrewsbury Town vs. Norwich City
Fulham vs. Doncaster Rovers
Tottenham Hotspur vs. Nottingham Forest
Paul Gorst
