Manager Luis Enrique has included two thirds of the famous attacking trio for his side's first competitive game of the season, with Neymar currently representing Brazil at the Olympic Games in Rio de Janeiro.
Sevilla, meanwhile, make four changes to the side that was just a minute away from winning the European Super Cup against Real Madrid on Tuesday, with Gabriel Mercado, Adil Rami, Sergio Escudero and Matias Kranevitter all coming into the team.
Sevilla: Sergio Rico; Mariano, Mercado, Rami, Escudero; Kranevitter, N'Zonzi; Vitolo, Franco Vazquez, Kiyotake; Vietto
Barcelona: Bravo; S. Roberto, Pique, Mascherano, Mathieu; Busquets, Rakitic, Iniesta; Turan, Messi, Suarez
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