The France international swapped sides in the summer on an initial loan deal, which is expected to be made permanent next summer for a fee of close to £175m.
Emery has set his side out in a 4-3-3 formation, with Julian Draxler being given the nod alongside Adrien Rabiot and Marco Verratti, while Lucas Moura and Christopher Nkunku again miss out on squad selection entirely.
Manager Leonardo Jardim appears to have gone with a three-man backline, meaning that Almamy Toure and Jorge will be given licence to power forward down the flanks from their starting wing-back positions.
PSG, currently six points better off than the reigning Ligue 1 champions, have won three and drawn four of their last eight visits to the principality.
Monaco: Subasic; Glik, Jemerson, Raggi; Toure, Fabinho, Moutinho, Tielemans, Jorge; Falcao, Keita Balde
Subs: Benaglio, Sidibe, Ndoram, Ghezzal, Lopes, Diakhaby, Carrillo
Paris Saint-Germain: Areola; Dani Alves, Marquinhos, Thiago Silva, Kurzawa; Verratti, Rabiot, Draxler; Mbappe, Cavani, Neymar
Subs: Trapp, Kimpembe, Meunier, Berchiche, Lo Celso, Pastore, Di Maria
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