The 32-year-old recently failed to agree new terms with the Spanish side and will depart on a free transfer.
"We would have liked him to continue as he's a respected and important part of this team, but it seems that our ideas are different and we must accept that," Goal.com quotes him as saying.
Demichelis has been linked with a return to his native Argentina to play for River Plate.
Restore Data
| Team | P | W | D | L | F | A | GD | PTS | |
| 1 | Leganes | 36 | 17 | 12 | 7 | 47 | 21 | 26 | 63 |
| 2 | EibarEibar | 35 | 17 | 7 | 11 | 57 | 40 | 17 | 58 |
| 3 | Espanyol | 35 | 15 | 13 | 7 | 51 | 36 | 15 | 58 |
| 4 | Real ValladolidValladolid | 35 | 17 | 7 | 11 | 41 | 31 | 10 | 58 |
| 5 | Real Oviedo | 35 | 14 | 13 | 8 | 45 | 30 | 15 | 55 |
| 6 | Sporting GijonSporting Gijon | 35 | 15 | 10 | 10 | 42 | 33 | 9 | 55 |
| 7 | ElcheElche | 35 | 15 | 9 | 11 | 36 | 32 | 4 | 54 |
| 8 | Racing Club de FerrolRacing de Ferrol | 35 | 14 | 12 | 9 | 43 | 41 | 2 | 54 |
| 9 | Racing de SantanderRacing | 35 | 15 | 8 | 12 | 55 | 50 | 5 | 53 |
| 10 | Burgos | 35 | 15 | 8 | 12 | 43 | 44 | -1 | 53 |
| 11 | Levante | 35 | 12 | 15 | 8 | 42 | 40 | 2 | 51 |
| 12 | TenerifeTenerife | 36 | 12 | 10 | 14 | 32 | 36 | -4 | 46 |
| 13 | Huesca | 35 | 9 | 15 | 11 | 30 | 25 | 5 | 42 |
| 14 | Real ZaragozaZaragoza | 35 | 10 | 12 | 13 | 33 | 33 | 0 | 42 |
| 15 | Eldense | 35 | 10 | 12 | 13 | 41 | 50 | -9 | 42 |
| 16 | AlcorconAlcorcon | 35 | 10 | 10 | 15 | 27 | 44 | -17 | 40 |
| 17 | CartagenaCartagena | 35 | 10 | 9 | 16 | 31 | 45 | -14 | 39 |
| 18 | MirandesMirandes | 35 | 9 | 11 | 15 | 39 | 49 | -10 | 38 |
| 19 | Amorebieta | 35 | 9 | 10 | 16 | 32 | 42 | -10 | 37 |
| 20 | Albacete | 35 | 8 | 12 | 15 | 40 | 50 | -10 | 36 |
| 21 | FC AndorraFC Andorra | 35 | 9 | 8 | 18 | 27 | 42 | -15 | 35 |
| 22 | Villarreal II | 35 | 8 | 9 | 18 | 32 | 52 | -20 | 33 |
| > Segunda Division Full Table | |||||||||
