Edinson Cavani and Ezequiel Lavezzi will once again lead the Napoli line, complemented by Marek Hamsik.
Andrea Dossena starts in a four-man midfield, alongside Walter Gargano, Juan Zuniga and Blerim Dzemaili.
The visitors also line up with a three-man attack, with Bergessio and Barrientos continuing alongside Alejandro Gomez.
Napoli: De Sanctis, Fernandez, Aronica, Campagnaro, Dzemaili, Gargano, Dossena, Zuniga, Cavani, Lavezzi, Hamsik
Catania: Carrizo, Spolli, Legrottaglie, Marchese, Belluschi, Lodi, Almiron, Izco, Gomez, Bergessio, Barrientos
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Napoli
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