Davide Nicola's side were promoted last season, but they face a tough test if they are to begin the new season without a defeat.
The Stadio Olimpico outfit missed out on a place in the Europe League this season, so they will be able to focus all their efforts on regaining a place in the Champions League.
Possible starting lineups
Livorno: Mazzoni, Gemiti, Valentini, Lambrughi, Emerson, Bernardini, Belingheri, Schiattarella, Benassi, Paulinho, Dionisi
Roma: De Sanctis; Maicon, Benatia, Castan, Balzaretti; Pjanic, De Rossi, Strootman; Gervinho, Totti, Florenzi
Sports Mole says: 1-2