The Brazilian Football Confederation (CBF) have ruled out appealing Neymar's four-match ban which would see him miss the remainder of the Copa America.
Despite Neymar's absence, Brazil qualified for the quarter-finals after a 2-1 victory over Venezuela.
"During a meeting on Sunday night between Neymar and the technical management, it was decided that the CBF would respect CONMEBOL's decision," said a CBF statement.
"Neymar is set to leave the Brazilian national football team headquarters this morning in Santiago de Chile."
Brazil will play Paraguay on Saturday for a place in the semi-finals.