Coach Carlo Ancelotti will head to the Mestalla with Beckham as a spectator, as the Ligue 1 outfit try to gain an advantage in the round-of-16 tie, with a place in the quarter-finals up for grabs.
PSG head into the meeting with the Spanish outfit on the back of one loss in their European campaign, while Valencia came second in Group F courtesy of four victories, one defeat and one draw.
Paris Saint-Germain: WWWWL
Possible starting lineups
Valencia: Alves; Pereira, Rami, R Costa; Ruiz, T Costa; Piatti, Banega, Guardado, Viera; Soldado
Paris Saint-Germain: Sirigu; Jallet, Alex, Sakho, Maxwell; Moura, Matuidi, Verratti, Pastore; Lavezzi, Ibrahimovic
Sports Mole says: 1-1