The centre-back is hoping to leave the club this month and made his intentions public yesterday by submitting a transfer request.
However, Rovers are adamant that the 27-year-old will not be exiting Ewood Park.
"Blackburn Rovers reiterate that team captain Christopher Samba is not for sale," read a statement on the club's official website.
"The player signed a new contract with the club less than a year ago which runs to June 2015."
Queens Park Rangers, Tottenham Hotspur and Paris Saint-Germain are all reportedly hoping to sign the former Congo international.